HUNTERTUTORING

Standard syllabus

Electrochemistry · Graduate · Chemistry

Topics

Thermodynamics and kinetics of electrode reactions

  • Electrochemical potential and Nernst equation
  • Standard electrode potentials and reference electrodes
  • Butler–Volmer equation and exchange current density
  • Tafel analysis and overpotential
  • Charge transfer coefficient and symmetry factor
  • Mass transport: migration, diffusion, convection
  • Limiting current and Cottrell equation
  • Rotating disk and ring-disk electrode theory
  • Electrochemical impedance spectroscopy (EIS) fundamentals
  • Double-layer structure and capacitance

Electroanalytical techniques

  • Cyclic voltammetry: reversible and irreversible systems
  • Linear sweep and differential pulse voltammetry
  • Square wave and stripping voltammetry
  • Chronopotentiometry and chronoamperometry
  • Electrochemical quartz crystal microbalance (EQCM)
  • Scanning electrochemical microscopy (SECM)
  • Potentiometric sensors and ion-selective electrodes
  • Amperometric biosensors and enzyme electrodes
  • Microelectrodes and ultramicroelectrode advantages
  • Data analysis: simulation with COMSOL or DigiElch

Energy storage and conversion

  • Battery fundamentals: intercalation, conversion, alloying
  • Lithium-ion chemistry: SEI formation and degradation
  • Solid-state batteries and electrolyte interfaces
  • Supercapacitors: EDLC vs pseudocapacitance
  • Fuel cells: ORR, HOR, and catalyst challenges
  • Water electrolysis and hydrogen production
  • CO₂ electroreduction mechanisms and products
  • Flow batteries: vanadium, organic redox couples
  • Electrode materials synthesis and characterization
  • In situ/operando spectroscopy of electrochemical interfaces

Corrosion and industrial electrochemistry

  • Corrosion thermodynamics: Pourbaix diagrams
  • Corrosion kinetics: polarization curves
  • Passivation and pitting corrosion
  • Cathodic protection and sacrificial anodes
  • Electroplating and electroless deposition
  • Electrochemical machining and synthesis
  • Chlor-alkali and chlorate industrial processes
  • Aluminum electrolysis (Hall–Héroult)
  • Electrochemical wastewater treatment
  • Scale-up from laboratory cells to industrial reactors

Pricing

Graduate-level rates are set on consultation. See the pricing page for K–12 and undergraduate rates.