Standard syllabus
Chemical kinetics · Graduate · Chemistry
Topics
Experimental kinetics
- Rate law determination: initial rates and integration methods
- Temperature dependence: Arrhenius, Eyring, and isokinetic relationships
- Isotope effects: primary, secondary, solvent, equilibrium
- Kinetic isotope effect theory and tunneling corrections
- Stopped-flow and rapid mixing techniques
- Relaxation methods: temperature-jump, pressure-jump
- Laser flash photolysis and pump–probe spectroscopy
- Matrix isolation kinetics
- Competition kinetics and relative rate measurements
- Error analysis and statistical treatment of kinetic data
Complex mechanisms
- Steady-state and pre-equilibrium approximations: validity criteria
- Rate laws for consecutive, parallel, and reversible reactions
- Chain reactions: initiation, propagation, termination, inhibition
- Explosion limits and branched chain mechanisms
- Oscillating reactions: Belousov–Zhabotinsky, Oregonator model
- Enzyme kinetics: Michaelis–Menten, inhibition, allostery
- Heterogeneous catalytic kinetics: Langmuir–Hinshelwood, Eley–Rideal
- Photochemical kinetics and quantum yields
- Radiation chemistry kinetics
- Microkinetic modeling of reaction networks
Gas-phase and solution dynamics
- Collision theory and hard-sphere model
- Transition state theory: partition function formulation
- Diffusion-controlled reactions: Smoluchowski theory
- Kramers rate theory for reactions in solution
- Marcus theory for electron transfer: reorganization energy
- RRKM and master equation for unimolecular reactions
- Molecular beam kinetics and crossed-beam studies
- State-resolved dynamics and steric effects
- Solvent effects on reaction rates and selectivity
- Ionic strength and activity coefficient effects
Industrial and environmental kinetics
- Reactor design: batch, CSTR, PFR kinetics
- Heterogeneous catalyst deactivation kinetics
- Combustion kinetics and atmospheric chemistry models
- Polymerization kinetics: chain-growth rate expressions
- Bioreactor kinetics and cell growth models
- Environmental degradation kinetics of pollutants
- Drug degradation and shelf-life kinetics
- Process safety: runaway reaction kinetics
- Scale-up effects on observed kinetics
- Real-time monitoring in manufacturing (PAT)
What each unit includes
Open a unit below for full materials. Typical resources:
- Study guide
- Exam Strategy
- Common Mistakes
- Worksheets
- Word problems
- Mixed Practice
- Multi-Unit Problems
- Review
- Practice test
- Answer key
Study units
Each unit includes a study guide, worksheets, review, practice test, and answer key. One unit is free; subscribe for the full class.
- Experimental kinetics
Rate law determination: initial rates and integration methods
Coming soon - Complex mechanisms
Steady-state and pre-equilibrium approximations: validity criteria
Coming soon - Gas-phase and solution dynamics
Collision theory and hard-sphere model
Coming soon - Industrial and environmental kinetics
Reactor design: batch, CSTR, PFR kinetics
Coming soon - Rigorous kinetic theory
Derivation of rate laws from mechanistic schemes
Coming soon - Advanced dynamics
Transition path sampling and committor analysis
Coming soon
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$1,162 · Chemical kinetics · 18 tutoring hrs
Study guides, worksheets, reviews, practice tests, and answer keys for 1 class. 18 tutoring hours (1 hr / week · semester). Bundle discount applied vs buying separately. Pay in full via Zelle.