Standard syllabus
Physical Chemistry I · Undergraduate · Chemistry
Topics
Laws of thermodynamics
- State functions, path functions, and exact differentials
- Zeroth law and temperature scales
- First law: internal energy, heat, and work
- Enthalpy, heat capacity, and Kirchhoff's equation
- Second law: entropy and Clausius inequality
- Third law and absolute entropy
- Gibbs and Helmholtz free energies
- Maxwell relations and thermodynamic identities
- Chemical potential and partial molar quantities
- Spontaneity criteria for chemical reactions
Phase equilibria and solutions
- Phase diagrams: unary and binary systems
- Clausius–Clapeyron equation
- Raoult's law and ideal solutions
- Henry's law and ideal dilute solutions
- Colligative properties: derivation and applications
- Activity, activity coefficients, and nonideality
- Gibbs phase rule and component analysis
- Liquid–vapor equilibrium and distillation (thermodynamic view)
- Solid–liquid equilibrium and eutectics
- Osmotic pressure and membrane equilibria
Chemical equilibrium and electrochemistry
- Equilibrium constant from standard Gibbs energy
- Temperature dependence: van't Hoff equation
- Multicomponent equilibrium and reaction coordinates
- Standard states for gases, solutions, and solids
- Electrochemical cells and thermodynamic cell potentials
- Nernst equation from chemical potential
- Reference electrodes and standard hydrogen electrode
- Ion activities and Debye–Hückel theory (introduction)
- Surface and interfacial thermodynamics (overview)
- Coupled reactions and equilibrium constraints
Chemical kinetics
- Rate laws and mechanistic interpretation
- Integrated rate laws and half-lives
- Temperature dependence: Arrhenius and Eyring equation (intro)
- Collision theory and transition state theory (overview)
- Steady-state approximation and pre-equilibrium
- Chain reactions: explosion limits and inhibition
- Catalysis: Michaelis–Menten and enzyme kinetics
- Fast reactions and relaxation methods (introduction)
- Reaction dynamics and potential energy surfaces (overview)
- Experimental methods: spectroscopic and flow techniques
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