Standard syllabus
Physical organic chemistry · Undergraduate · Chemistry
Learning objectives from the Physical organic chemistry syllabus, grouped by unit. Click an objective for study materials.
Learning objectives
Click an objective for study materials.
Structure and bonding in organic chemistry
- Resonance, inductive, and hyperconjugative effects — Resonance, inductive, and hyperconjugative effects
- Aromaticity: Hückel's rule and antiaromaticity — Aromaticity: Hückel's rule and antiaromaticity
- Steric effects: A-values, Thorpe–Ingold effect — Steric effects: A-values, Thorpe–Ingold effect
- Torsional strain and conformational analysis — Torsional strain and conformational analysis
- Bond dissociation energies and radical stability — Bond dissociation energies and radical stability
Reaction mechanisms and kinetics
- Reaction coordinates and transition states — Reaction coordinates and transition states
- Hammond postulate and Curtin–Hammett principle — Hammond postulate and Curtin–Hammett principle
- Kinetic vs thermodynamic control — Kinetic vs thermodynamic control
- Rate laws and mechanism determination — Rate laws and mechanism determination
- Steady-state and pre-equilibrium approximations — Steady-state and pre-equilibrium approximations
Reactive intermediates
- Carbocations: generation, trapping, and spectroscopy — Carbocations: generation, trapping, and spectroscopy
- Carbanions: formation, aggregation, and reactivity — Carbanions: formation, aggregation, and reactivity
- Free radicals: initiation, propagation, termination — Free radicals: initiation, propagation, termination
- Radical clocks and radical probe experiments — Radical clocks and radical probe experiments
- Carbenes: singlet vs triplet, insertion reactions — Carbenes: singlet vs triplet, insertion reactions
Stereochemistry and pericyclic reactions
- Conformational effects on reactivity — Conformational effects on reactivity
- Stereoelectronic effects: anomeric, gauche, β-silicon effect — Stereoelectronic effects: anomeric, gauche, β-silicon effect
- Neighboring group participation — Neighboring group participation
- Asymmetric induction: Cram's rule, Felkin–Anh model — Asymmetric induction: Cram's rule, Felkin–Anh model
- Pericyclic reactions: electrocyclic, cycloaddition, sigmatropic — Pericyclic reactions: electrocyclic, cycloaddition, sigmatropic
What each unit includes
Open a unit below for full materials. Typical resources:
- Study guide
- Exam Strategy
- Common Mistakes
- Worksheets
- Word problems
- Mixed Practice
- Multi-Unit Problems
- Review
- Practice test
- Answer key
Study units
Each unit includes a study guide, worksheets, review, practice test, and answer key. One unit is free; subscribe for the full class.
- Structure and bonding in organic chemistry
Resonance, inductive, and hyperconjugative effects
Coming soon - Reaction mechanisms and kinetics
Reaction coordinates and transition states
Coming soon - Reactive intermediates
Carbocations: generation, trapping, and spectroscopy
Coming soon - Stereochemistry and pericyclic reactions
Conformational effects on reactivity
Coming soon
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